A line in R^2 has an equation of the form ax + by + c = 0, where a and b must not both be 0.

If a ≠ 0 then we can divide by a and write the equation as x + b'y + c' = 0. The map taking this line to the point (b',c') in R^2 is one chart.

If b ≠ 0 then we can divide by b and write the equation as a'x + y + c' = 0. The map taking this line to the point (a',c') in R^2 is also a chart.

Those two charts together specify the manifold structure.