this doesn't quite make sense: 'first vector is "r" and the second "theta"' because those are numbers, not vectors. I think what you mean rather is that we have
different basis vectors at each point. One of the basis vectors,

, at (x, y), is the unit vector whose direction is
away from the origin, along the line y= x, and the other,

is the unit vector perpendicular to that in the direction of increasing angle. Those. I presume, are your "er" and "e(theta)", respectively.
But I don't know what you mean by "Er" and "i"? did you mean "er" again? And is "i" the unit vector in the x-direction?